If it was slick feeling it was probably antifreeze. You can also touch the tip of your tongue with it and if it taste sweet that's what it is. Sounds like a heater core
Or... It could be the evaporator drain tube clogged and it's not letting the condensation(water) from the evaporator drip since you said you ran the defroster and its overflowing so to speak from the ac box
Or... It could be the evaporator drain tube clogged and it's not letting the condensation(water) from the evaporator drip since you said you ran the defroster and its overflowing so to speak from the ac box