The actual valve job would be done by a qualified automotive machine shop with lots of experience and expensive equipment. It is usually fairly inexpensive and about $350. should do a typical 3.5-3.7 head including new seals & guides.
As for DIY labor to remove and replace the head a little experience, a manual, a good selection of metric tools, and a little patience should get the job done. In addition to a decent torque wrench the following specialty tools will also be required:
A. Compact damper puller. (Pulls damper w/o removing radiator or condenser. I bought an OTC puller from zoro.com)
B. Something to hold damper from rotating. (I used a big pipe wrench. Don't ask)
C. Damper installer. (I used metric all-thread, heavy duty nut, & heavy washer)
D. Torque angle tool. (The really cheap ones are junk & inaccurate. Frustrating!)
E. Metric male hex key socket set.
F. A good assortment of 1/4" socket extensions including some wobble. (Intake)
When I did mine it was one Saturday to pull head. Sunday I port matched the head & exhaust manifold, did the pre-cat delete, and cleaned a few parts. Also because they were easily accessible I installed a new alternator and starter. Monday morning the head went to the machine shop and the PCM & throttle body shipped by air to Supermodulation for some of his magic. During the week I picked up the head, collected more parts, & finished cleaning parts. Saturday reassembled the truck, it started instantly, and ran perfectly. In addition to the required gaskets, damper bolt, and head bolts I also replaced the timing set, hoses, belt tensioner, idler pulley, belt, plugs, plug boots, thermostat, alternator, and starter.
My manual (Haynes) said with my 2WD I needed to remove the steering gear to remove the pan. WRONG! Before removing the damper just unbolt the motor mounts & jack up the front of the engine under the damper to easily pull the pan.
Go for it.